Assertion :The heat of formation of water is equal to the heat of neutralisation of a strong acid with a strong base. Reason: Water involves to a very small extent while H⊕ ions from an acid combine very rapidly with ⊖OH from a base to form H2O.
A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution
The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion The enthalpy of neutralization is the change in enthalpy that occurs when one equivalent of an acid and one equivalent of a base undergo a neutralization reaction to form water and a salt. The standard enthalpy change of neutralization for a strong acid and base is -13.7 kcal/mol When a powerful acid and a powerful base react, enthalpy change is unique. It may be more clear in the example below, NaOH+HCl→NaCl+H2O when we consider the above reaction it is clear the only reaction we can see inside this is,