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Question

Assertion :The molar mass obtained for benzoic acid in benzene is found to be nearly 244. Reason: Benzoic acid has the molecular formula C6H6O2

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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Solution

The correct option is C Assertion is correct but Reason is incorrect
Assertion is correct. In benzene, the benzoic acid forms dimer. Hence, the observed molecular weight is twice the actual molecular weight(2×122=244).
Reason is incorrect. The actual molecular formula of benzoic acid is C7H6O2

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