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Question

Assertion :The pH of an acetic acid buffer solution cannot be more than 7. Reason: Acidic buffer consists of a weak acid and its salt with a strong base.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
The pH of an acetic acid buffer solution cannot be more than 7.
An acidic buffer consists of a weak acid and its salt with a strong base.
For example, consider an acidic buffer consisting of a weak acid (acetic acid) and its salt (sodium acetate) with a strong base (sodium hydroxide).
Sodium acetate completely ionizes to provide sodium ions and acetate ions.
CH3COONaCH3COO+Na+
Acetic acid is feebly ionised.
CH3COOHCH3COO+H+
Since protons are formed in above ionisation, an acidic buffer consists of more hydrogen ions than hydroxide ions.
[H+]>[OH]
[H+]>107 M
pH<7

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