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Question

Assertion :TlCl3 is more stable than TlCl Reason: +1 oxidation state of Tl is more stable than +3.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
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C
Assertion is correct but Reason is incorrect.
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D
Assertion is incorrect but Reason is correct.
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Solution

The correct option is D Assertion is incorrect but Reason is correct.
TlCl (+1 oxidation state) is more stable than TlCl3 (+3 oxidation state). Due to inert pair effect.
So +1 oxidation state is more stable than +3 oxidation state.
Hence option D is correct.

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