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Question

Assertion :Treatment of cis-2-butene with cold,dilute and alkaline KMnO4 solution gives a meso-2,3-butanediol. Reason: MnO4 forms a cyclic intermediate with alkene.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
A meso compound is a molecule with multiple stereocenters that is superimposable on its mirror image.

Assertion - Treatment of cis-2-butene with cold, dilute and alkaline KMnO4 solution gives a meso-2,3-butanediol. This statement is true.

Reason - MnO4 forms a cyclic intermediate with alkene. This statement is true.

Formation of cyclic intermediate restricts rotation and switching of CH3 and OH groups which is why plane of symmetry exists. So both statements are correct and reason is correct explanation of assertion.


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