Assertion :When 1.0 mol of NaCl is doped with 10−3 mol SrCl2, the number of cationic sites remaining vacant is 10−3. Reason: Each SrCl2 unit produces two cationic vacancy.
A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution
The correct option is C Assertion is correct but Reason is incorrect
One cation vacancy is produced by one Sr2+ because the charge neutralization is maintained. Hence, when 1mol of NaCl is doped with 10−3molSrCl2; the cationic sites remaining vacant is 10−3.