Assertion :When 1 mole of hypophosphorous acid is treated with excess of iodine in acidic solution, 1 mole of iodine is reduced; on making the solution alkaline, another mole of iodine is consumed. Reason: H3PO2+I2+H2O⟶H3PO3+2I−+2H+H3PO3+I2+2OH−⟶H3PO4+2I−+H2O