Assertion :When $c i s - 3, 4 - d i m e n t h y l - 3 - h e x e n e$ is hydrogenated in presence of a Ni catalyst, a $m e s o$ hydrocarbon is obtained, However, when $t r a n s - 3, 4 - d i m e t h y l - 3 - h e x e n e$ is hydrogenated with Ni catalyst, a racemic mixture of product is obtained Reason: Catalytic hydrogenation occur in syn orientation

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion

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Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

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Assertion is correct but Reason is incorrect

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Both Assertion and Reason are incorrect

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Solution

The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
Syn orientation is obtained during catalytic hydrogenation as the reaction occurs on the surface of the catalyst. Thus, cis alkene gives $m e s o$ product and the trans alkene gives the racemic product.

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Similar questions

Assertion (A) The enthalpy of reaction remains constant in the presence of a catalyst.

Reason (R) A catalyst participating in the reaction forms different activated complex and lowers down the activation energy but the difference in enrgy of reactant and product remains the same.

(a) Both assertion and reason are correct and the reason is correct explanation of assertion
(b) Both assertion and reason are correct, but reason does not explain assertion.
(c) Assertion is correct, but reason is incorrect
(d) Both assertion and reason are incorrect
(e) Assertion is incorrect but reason is correct.

Assertion (A) Boiling points of alcohols and ethers are high.
Reason (R) They can form intermolecular hydrogen-bonding.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

ASSERTION: n-Pentane and n-Hexane belong to a homologous series.

REASON: n-Pentane and n-Hexane belong to the same class of hydrocarbons and they differ by a - $C H_{2}$ - group.

Q. Assertion: The compressibility factor for

H_{2}

and

H e

(1 + \frac{P b}{R T})

Reason: The compressibility factor for

H_{2}

and

H e

can be derived from Van der Waal's equation.

Assertion (A) IUPAC name of the compund
$C H_{3} - C H | C H_{3} - O - C H_{2} - C H_{2} - C H_{3}$ is 2-ethoxy-2-methylethane
Reason (R) In IUPAC nomenclature, ether is regarded as hydrocarbon derivative in which a hydrogen atom is replaced by - OR or - 0AR group [where, R = alkyl group and Ar = aryl group].
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

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