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Question

Assertion :White precipitate of Mg(OH)2 is insoluble in excess of sodium hydroxide but readly soluble in solution of ammonium salts. Reason: Mg(OH)2 is very sparingly soluble in water.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is incorrect but Reason is correct
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D
Both Assertion and Reason are correct
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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
Magnesium sulphate reacts with disodium hydrogen phosphate in presence of ammonium hydroxide, a insoluble white crystalline precipitate of magnesium ammonium phosphate is formed.
MgSO4+Na2HPO4+NH4OHMg(NH4)PO4(white ppt)+Na2SO4+H2O
Thus both assertion reasons are correct and reaction is the correct explanation for assertion.

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