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Question

Assume that the de-Broglie wave associated with an electron can form a standing wave between the atoms arranged in a one dimensional array with nodes at each of the atomic sites. It is found that one such standing wave is formed if the distance d between the atoms of the array is 2A. A similar standing wave is again formed if d is increased to 2.5A but not for any intermediate value of d. Find the energy of the electron in electron volts and the least value of d for which the standing wave of the type described above can form.

A
151 eV,0.5 A.
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B
1151 eV,0.5 A.
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C
251 eV,0.5 A.
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D
1351 eV,0.5 A.
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Solution

The correct option is A 151 eV,0.5 A.
As nodes are formed at each of the atomic sites, hence
20A=n(λ/2)(1)
and 2.50A=(n+1)λ/2
2.5/2=nt1/n.5/4=n+1/n or n=4
Hence from equation (1)
20A=4λ/2 i.e. λ=10A
Now, de Brogile wavelength is given by,
λ=h/2mk or k=h2/λ2=2m
k=(6.63×1034)2/(1×1010)2×2×9.1×1031×1.6×1019eV
k=151eV
θ will be minimum, when
n=1, dmin=λ/2=10A/2=0.50A

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