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Question

Assuming that petrol is octane (C8H18) and has a density of 0.8gmL1, 1.425 litre of petrol on combustion will consume:

A
100 mole of oxygen
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B
125 mole of oxygen
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C
150 mole of oxygen
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D
175 mole of oxygen
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Solution

The correct option is B 125 mole of oxygen
The equation looks like this CnH3n+2+(3n+12)O2nCO2+(n+1)H2O
For others,
C8H18+(252)O2(8)CO2+(9)H2O1mol252mole
Mass of octane =PV=0.8×1425=1140g.
No. of moles of octane =1140114.23=9.97
Now, 1 mol octane consumes 252 mol of O2.
9.97 mol octane consumes 252×9.97=124 moles of O2

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