At 0∘C, ice and water are in equilibrium and enthalpy change for the process H2O(s)⇌H2O(l)is6.0kJmol−1. The entropy change for the conversion of ice into liquid water is
A
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B
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C
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D
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Solution
The correct option is C H2O(s)fusion⇌H2O(l);ΔSfus=6.00kJmol−1=6000Jmol−1Tf=0∘C=(0+273)K=273KΔSfus=ΔHfusTf=6.00kJmol−1273K=(600Jmol−1)(273K)=21.98kJK−1mol−1