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Byju's Answer
Standard XII
Chemistry
Third Law of Thermodynamics
At 0∘ C, if t...
Question
At
0
o
C
, if the enthalpy of fusion of ice is 1365
k
c
a
l
/
m
o
l
. Then, the molar entropy change for melting of ice at
0
o
C
in
k
J
/
m
o
l
is
.
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Solution
Change in entropy for a phase transformation is given as:
△
S
transformation
=
△
H
transformation
T
putting all the values from question we get:
△
S
f
u
s
i
o
n
=
△
H
f
u
s
i
o
n
T
△
S
f
u
s
i
o
n
=
1365
273
△
S
f
u
s
i
o
n
=
5
k
c
a
l
/
m
o
l
as
1
c
a
l
=
4.18
J
△
S
f
u
s
i
o
n
=
20.9
k
J
/
m
o
l
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0
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At
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Q.
Calculate the change in entropy for fusion of 1 mole of ice. The melting point of ice is 273 K and molar enthalpy of fusion for ice = 6.0 kJ
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