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Question

At 200oC a compound 'A' (molar mass =100gmol1) in the vapour phase dissociates as A(g)2B(g)+C(g).
The vapour density at 200oC is found to be 30. The percent dissociation of the compound A at 200oC will be?

A
33%
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B
66%
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C
87%
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D
100%
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Solution

The correct option is A 33%
The given vapour density(d) is the observed one.
A(g)2B(g)+C(g)
%α=Ddd(y1)×100
where,
D is calculated vapour phase i.e.
100X2=200.
y is number of moles of product per mole reactant.
%α=1003030×2
%α=33%
Option A is correct answer

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