At 25oC, a 0.01 mole sample of a gas is compressed in volume from 4.0L to 1.0L at constant temperature. What is work done for this process if the external pressure is 4.0 bar?
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Solution
External pressure (P)=4 bar=3.95 atm
Initial volume (V1)=4L
Final volume (V2)=1L
No. of moles (n)=0.001 mole
R=8.314L−atmK−1mol−1
For an isothermal process,
Work done (W)=−PΔV
∴W=−3.95×(1−4)=11.85L.atm=1200.7605=1.2×103J
Hence the work done for the given process is 1.2×103J.