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Question

At 25oC, the vapour pressure of methyl alcohol is 96.0 torr. What is the mole fraction of CH3OH in a solution in which the (partial) vapor pressure of CH3OH is 23.0 torr at 25oC?

A
0.24
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B
0.25
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C
0.26
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D
0.27
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Solution

The correct option is A 0.24
According to Raoult's law, p=p0×x

p = partial vapour pressure of methanol

p0= pure vapour pressure of methanol

x = mole fraction of methanol.

Substitute values in the above expression

23.0=96.0×x

Hence, the mole fraction of methanol is 0.24.

Option A is correct.

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