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Question

At 298.2 K the relationship between enthalpy of bond dissociation (in kJ mol−1) for hydrogen (EH) and its isotope, deuterium (ED), is best described by

A
EHED7.5
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B
EH=2ED
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C
EH=12ED
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D
EH=ED
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Solution

The correct option is A EHED7.5
Enthalpy of bond dissociation of hydrogen = 435.88 kJmol1
Enthalpy of bond dissociation of deuterium = 443.35 kJmol1
EH=ED7.47
EHED7.5

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