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Question

At 298 K, the heat of solution of MgSO4 (s) is -91.21 KJ mol1 and that of MgSO4. 7 H2O (s) is 13.81 KJ mol1. Calculate heat of hydration of MgSO4 i.e., ΔH for the reaction MgSO4(s)+7H2O(l)MgSO4.7H2O(s)


A
-105.02 KJ mol1
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B
105.02 KJ mol1
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C
-77.40 KJ mol1
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D
77.40 KJ mol1
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Solution

The correct option is A -105.02 KJ mol1
MgSO4(s)+7H2O(l)MgSO4.7H2O(s)
ΔH= Heat of solution of MgSO4(s) - Heat of solution of MgSO4(s).7H2O(s)
=91.21KJmol113.81KJ =105.02KJmol1

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