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Question

At 300 K, a certain I order reaction is 50% completed in 20 minutes. At 350 K, the same reaction is completed in 5 minutes. The ratio of the rate constant at 350 K and 300 K is:

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Solution

At 300 K, a certain I order reaction is 50% completed in 20 minute.
At 350 K, the same reaction is 50% completed in 5 minutes.
The ratio of the half life periods is 5min20min=14
The ratio of the rate constants is the reciprocal of the ratio of the half lives.
The ratio of rate constant at 350 K and 300 K is 114=4

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