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Question

At 80o C, the vapour pressure of pure liquid A is 520 mmHg and that of pure liquid B is 1000 mmHg. If a mixture solution of A and B boils at 80o and 1 atm pressure, the amount of A (mole percent) in the mixture is:

A
50%
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B
54%
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C
32%
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D
44%
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Solution

The correct option is B 50%
Let the amount of A in the mixture be χA and B be the χB.

PT=760=PoAχA+PoBχB

760=520χA+1000(1χA)

480χA=240

χA=12 or 50%.

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