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Question

At 80C, the vapour pressure of pure benzene is 753 mm Hg and of pure toluene 290 mm Hg. Calculate the composition of a liquid in mole percent which at 80 is in equilibrium with vapour containing 30 mole percent of benzene.

A
24, 56
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B
26 ,54
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C
56 24
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D
34 ,76
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Solution

The correct option is A 24, 56
Mole % of benzene=30%of solution
Moles of benzene=30*80/100=24
Moles of Toluene=70*80/100=56
Composition of benzene and Toluene are 24 moles and 56 moles respectively.

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