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Question

At a certain temperature 2 moles of carbonmonoxide and 3 moles of chlorinw were allowed to reach equilibrium according to the reaction CO(g)+Cl2COCl2 in a 5 lit vessel. At equilibrium if one mole of CO is present then equilibrium constant for the reaction is ____

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Solution

CO(g)+Cl2CaCl2
at t=0 2moles 3mole -
at eqn 1mol 2mol 1mol
the mixture is contained at 5 litre vessel
[CO]=15molL1,[Cl2]=35molL1
[CoCl2]=15molL1
KC=[CoCl2][CO][Cl2]=3515×35=1.66mol1L

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