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Question

At a certain temperature the equilibrium constant Kc is 0.25 for the reaction A2(g)+B2(g)C2(g)+D2(g)
If we take 1 mole of each of the four gases in a 10 litre container, what would be equilibrium concentration of A2(g).

A
0.0
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B
0.13
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C
0.25
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D
1
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Solution

The correct option is B 0.13
Reaction Quotient, Q=1×11×11
Q>Kc so reaction will proceed in backward direction
A2(g)+B2(g)C2(g)+D2(g)concentration at equilibrium1.0+x101.0+x101.0x101.0x10
0.25=(1x10)2(1+x10)2
0.5=1x1+x
0.5+0.5 x=1x
1.5 x=0.5
x=0.333
[A2(g)]=1+x10
[A2(g)]=1.33310=0.13

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