At a certain temperature the equilibrium constant Kc is 0.25 for the reaction A2(g)+B2(g)⇌C2(g)+D2(g) If we take 1 mole of each of the four gases in a 10 litre container, what would be equilibrium concentration of A2(g).
A
0.0
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B
0.13
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C
0.25
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D
1
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Solution
The correct option is B 0.13 Reaction Quotient, Q=1×11×1⇒1 ∵Q>Kc so reaction will proceed in backward direction A2(g)+B2(g)⇌C2(g)+D2(g)concentration at equilibrium1.0+x101.0+x101.0−x101.0−x10 0.25=(1−x10)2(1+x10)2 ⇒0.5=1−x1+x ⇒0.5+0.5x=1−x ⇒1.5x=0.5 ⇒x=0.333 [A2(g)]=1+x10 [A2(g)]=1.33310=0.13