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Question

At a given temperature, total vapour pressure (in torr) of a mixture of volatile components A and B is given by PTotal=120−75XB hence, the vapour pressure of pure A and B respectively (in Torr) are:

A
120,75
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B
120,195
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C
120,45
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D
75,45
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Solution

The correct option is C 120,45
PTotal=12075XB=PoAXA+PoBXB

But XA=1XB

Hence, PTotal=12075XB=PoA(1XB)+PoBXB=PoA(PoAPoB)XB

Hence, PoA=120 and PoB=12075=45

Hence, the correct option is C

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