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Question

At constant volume, the specific heat of a gas is 0.025 cal K1 g1 and its molecular weight is 120 g mol1. The atomicity of the gas is:
Given: R = 2 cal K1mol1

A
Diatomic
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B
Triatomic
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C
Monoatomic
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D
None of the above
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Solution

The correct option is C Monoatomic
We know that molar heat capacity at constant volume,
(Cv,m) = Specific heat at constant volume × Molecular weight.

= 0.025×120=3 cal K1 mol1....(i)

Also, CpCv=R
Cp=R+Cv
= Cp=2+3=5 cal K1 mol1.....(ii)

Now, CpCv=γ

Using equation (i) and (ii)
γ=53=1.67
This value shows that the gas is monoatomic.

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