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Question

At high pressure, van der Waal's equation for one mole of the gas becomes:

A
PV=RT
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B
PV=RT+aV
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C
PV=RTaV
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D
PV=RT+Pb
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Solution

The correct option is D PV=RT+Pb
(P+an2V2)(Vnb)=nRT(P+aV2)(Vb)=RT for 1 mol gasAt high pressure,(P+aV2)=PP(Vb)=RTPV=RT+Pb

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