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Question

At high temperature of 727 C, a dynamic equilibrium exists between CO,CO2 and solid carbon.
C(s)+CO2(g)2CO(g); KC=0.1M
Then value of KP at given temperature is :

A
82.1 atm
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B
0.821 atm
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C
0.0821 atm
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D
8.21 atm
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Solution

The correct option is D 8.21 atm
We know from relation between Kp and Kc
Kp=Kc(RT)Δn
Where,
Δn= Number of moles of product in gaseous state - number of moles of reactant in gaseous state
(Δn)g=21=1

We know,R=0.0821 L atm mole 1K1Temperature (given),T=727 C=(727+273) K=1000 KKp=(0.1)(0.0821×1000)1 atmKp=8.21atm

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