At higher altitude, boiling point of water is 95oC. The mass in gram of NaCl (α=0.8) added to 100g of water (Kb=0.52K kg mol−1) in order to raise the boiling point to 100oC is: (M.W ofNaCl=58.5u)
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Solution
We know, ΔTB=iKbm
Where, m=molality
Given, α=0.8
So, i=1+α=1.8 ∴5=1.8×0.52×1000100×W58.5 ⇒W=5×100×58.51.8×0.52×1000=31.25g