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Byju's Answer
Standard XII
Chemistry
Nernst Equation
At pH = 2, ...
Question
At
p
H
=
2
,
E
Quinhydrone
will be:
Given:
E
o
Quinhydrone
=
1.30
V
A
1.36
V
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B
1.30
V
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C
1.42
V
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D
1.20
V
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Solution
The correct option is
C
1.42
V
For the chemical equation for this reaction is as follows:
Hydroquinone
⇌
Quinone
+
2
H
+
+
2
e
−
Therefore the nernst equation is:
E
=
E
0
+
0.0591
p
H
=
1.30
+
0.0591
×
2
=
1.418
≈
1.42
Hence, the correct option is
C
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Similar questions
Q.
At
p
H
= 2,
E
∘
Q
u
i
n
h
y
d
r
o
n
e
=
1.30
V
,
E
Q
u
i
n
h
y
d
r
o
n
e
will be:
Q.
For the half cell
E
o
=
1.30
V
. At
p
H
=
3
, electrode potential is:
Q.
At
p
H
=
2
,
E
Q
u
i
n
h
y
d
r
o
n
e
will be (
E
Q
u
i
n
h
y
d
r
o
n
e
=
1.30
V
)
[Assume that the concentration of hydroquinone and quinone is
1
M
]
Q
H
2
→
Q
+
2
H
+
+
2
e
−
, where
Q
H
2
and
Q
stand for hydroquinone and quinone respectively. (Given,
2.303
R
T
F
=
0.06
)
Q.
For the half-cell:
At
p
H
=
2
, electrode potential is:
Q.
The pH of
1.0
M
N
a
H
S
O
4
solution will be:
(Given that
K
1
and
K
2
for
H
2
S
O
4
equal to
∞
and
10
−
2
respectively)
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