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Question

At room temperature, ammonia gas at one atmosphere pressure and hydrogen chloride at P atmospheric pressure allowed to effuse through identical pinholes from opposite ends of a glass tube of one metre length and uniform section. NH4Cl is first formed at a distance of 60 cm from the end through which HCl gas is sent in. What is the value of?

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Solution

Using Graham's law of diffusion,
rHClrNH3=MNH3MHCl×PHClPNH3
=6040=0.682×PHCl
PHCl=2.198 atm

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