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Question

At the triple point of a pure substance, the number of degrees of freedom is

A
2
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B
1
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C
0
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D
3
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Solution

The correct option is C 0
Gibb's phase rule:
F+P=C+2

Where, F= degree of freedom, P = no.of phases

C = no. of components

For pure substance, no. of components, C = 1

At triple point, no. of phases,P=3

F+3=1+2

Degree of freedom, F=0

Points To Remember:
(i) On P-T diagram, triple point and circuit point both are points.

(ii) On P-V diagram, triple point is a line and critical poin is a point

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