The correct option is A 4:30
At 4:30, the angle between the hour hand and the minute hand is less than 90o and hence is acute.
Whereas, the angle made between the hour hand and the minute hand at 6:00 is 180o, which is a straight angle.
At 9:00, the angle between the hour hand and the minute hand is 90o
At 5:00, the angle between the hour hand and the minute hand is more than 90o, therefore an obtuse angle.