The correct option is D 4∘C
Water on cooling contracts upto 4∘C and on further cooling, it starts to expand till it freezes into solid ice at 0∘C. This property of water is called anomalous expansion.
Density of water gradually increases as we cool it. At 4∘C it reaches at a maximum density. When we further cool it below 4∘C, it starts to expand and the density of water starts decreasing.
Thus water has the maximum density at 4∘C.