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Question

Atomic numbers of elements A, B, C and D are 3, 9, 11 and 17 respectively. Identify two pairs amongst the elements which have similar chemical properties. Which pair is likely to be metallic in character?


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Solution

In order to identify two pairs amongst the elements which have similar chemical properties and identify metallic character, number of electrons present in the outermost shell (valence electrons) should be known.

  • The elements which have the same number of valence electrons exhibit similar chemical properties. This is because only valence electrons participate in the chemical reactions and influence chemical properties of any substance.

To find out the valence electrons, electronic configuration should be written first.

  • Electronic configuration: The distribution of electrons in the orbits around the nucleus in an atom.

Step-1: Write electronic configuration

Atomic number= Number of protons

Also, Number of protons= Number of electrons for an atom

  • Begin to fill electrons from the innermost shell (or K shell) to outermost shell
  • The maximum number of electrons that can be accommodated in first, second and third shells are 2, 8, 18 respectively.
  • The electrons are filled in shells in a sequential manner.
  • The maximum number of electrons in a valence shell can be 8.

Step-2: Find out the valence shell and its electrons

  • The outermost shell is the valence shell and the electrons in it are the valence electrons.

Metallic/ Non-metallic character:

  • If the number of valence electrons is less than 4, the element is a metal.
  • If the number of valence electrons is 4 or more than 4, the element is a non-metal.
ElementsNumber of electronsElectronic configurationValence electronsMetallic/ Non-metallic
A32, 11Metallic
B92, 77Non-metallic
C112, 8, 11Metallic
D172, 8, 77Non-metallic

Therefore, pair wise results are as follows:

Pair

Pair

constituents

Chemical properties

Nature of

Pair

1A and C (1 valence electron)A and C have similar chemical propertiesMetallic pair
2B and D (7 valence electrons)B and D have similar chemical propertiesNon-metallic pair

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