Azulene is a non-benzenoid aromatic compound which has large resonance energy and a large dipole moment. It is a 10 pi electron system. It is common to suggest that azulene is made up of the “fusion” of
two aromatic ions, both with 6 π electrons, cycloheptatrienyl
(tropylium) cation and cyclopentadienyl anion.
It exhibits aromatic properties: (i) the peripheral bonds have similar lengths and (ii) it undergoes Friedel-Crafts-like substitutions.