Compare the total number of atoms of each element on the reactant side and the product side.
Element
Reactant side
Product side
Nitrogen()
2
1
Hydrogen()
2
3
Now, stoichiometric coefficients are added to molecules containing an element that has a different number of atoms on the reactant side and the product side.
The coefficient must balance the number of atoms on each side.
In order to balance Hydrogen() multiply on the product side and multiply 3 with hydrogen on the left-hand side.
Element
Reactant side
Product side
Nitrogen()
2
1 X 2
Hydrogen()
2 X 3
3 X 2
Reaction becomes,
The number of atoms of the elements on the reactant and product side is equal.