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Solution
The correct option is CCr2O2−7(aq)+3SO2−3(aq)+8H+(aq)→2Cr3+(aq)+3SO2−4(aq)+4H2O(aq)
So , oxidizing agent : Cr2O7
Reducing agent : SO3
n-factor :
for Cr2O2−7:6 , for SO3:2
Equalising the decrease/increase in oxidation number : Cr2O2−7+SO2−3→2Cr+3+SO2−4
Cross multiply the oxidising or reducing agent with simplified n-factor number, Cr2O2−7+3SO2−3→2Cr+3+3SO2−4
Balance oxygen atoms. Cr2O2−7+3SO2−3→2Cr+3+3SO2−4++4H2O
Balance Hydrogen atoms. Cr2O−27+3SO2−3+8H+→2Cr3++3SO2−4++4H2O
balance charge
charge in reactant side = 0
charge in product side = 0
so the balanced equation is Cr2O2−7+3SO−23+8H+→2Cr3++3SO2−4+4H2O