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Question

Base catalysed aldol condensation occurs with:

A
benzaldehyde
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B
2-methyl propanal
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C
2, 2-dimethylpropanal
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D
Formaldehyde
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Solution

The correct option is B 2-methyl propanal
Benzaldehyde, 2, 2-dimethylpropanal and formaldehyde do not contain alpha hydrogen atom. Hence, they undergo cannizaro reaction on treatment with base.
2-methyl propanal contains an alpha carbon atom. Hence, on treatment with base, it undergoes aldol condensation reaction.
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