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Question

Based on the values of bond energies given, ΔfHo of N2H4(g) is:
Given: NN=159 kJ mol1 ; HH=436 kJ mol1
NN=941 kJ mol1 ; NH=398 kJ mol1

A
700 kJ mol1
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B
62 kJ mol1
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C
98 kJ mol1
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D
711 kJ mol1
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Solution

The correct option is B 62 kJ mol1
N2(g)+2H2(g)N2H4(g)
ΔfH(N2H4(g))
=Sum of bond energies of bonds being broken - sum of the bond energies of the bonds being formed=((B.E.)NN+2×(B.E.)HH)((B.E.)NN+4×(B.E.)NH)=(941+2×436)(159+4×398)
=18131751=62 kJ mol1

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