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Question

Basic strength of NH4OH in presence of NH4CI

A
Increase
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B
Remains unchanged
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C
Decreases
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D
Some times increases or sometimes decrease
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Solution

The correct option is C Decreases
While the NH4OH is weak base it does not ionises completely. Thus due to presence of common ion NH4+ in NH4Cl, it supresses the ionisation of weak base NH4OH in order to decrease the OH-concentration so that higher group cations will not get precipitated.

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