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Question

Bauxite ore is made up of Al2O3+SiO2+TiO2+Fe2O3. This ore is treated with conc.NaOH solution at 500K and 35 bar pressure for few hours and filtered, the species present are:

A
NaAl(OH)4 only
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B
Na2Ti(OH)6 only
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C
NaAl(OH)4 and Na2SiO3 both
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D
Na2SiO3 only
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Solution

The correct option is C NaAl(OH)4 and Na2SiO3 both
TiO2 and Fe2O3 are basic oxides. So they will not react with NaOH. Al2O3 is amphoteric oxide and SiO2 is acidic oxide. So they will react with NaOH
Al2O3+NaOHNaAl(OH)4
SiO2+NaOHNa2SiO3

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