ΔGΔHΔS(I)+ve(i)−ve(P)∞(II)∞(ii)0(Q)+ve(III)0(iii)∞(R)−ve(iv)−ve(iv)+ve(S)0 The correct set for melting of ice at −15∘C is:
A
(IV) (iii) (P)
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B
(I) (iv) (R)
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C
(I) (iv) (Q)
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D
(IV) (ii) (P)
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Solution
The correct option is C(I) (iv) (Q) Normally ice melts above or at 0∘C. So, if it's melting at −15∘⇒ non spontaneous. ⇒ΔG=+ve. Due to melting, the entropy is increasing and melting is endothermic ⇒ΔS=+ve. ⇒ΔH=+ve.