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LIST-ILIST-II(P) PCl3F2,PCl2F3(1)Hybridisation of central atom same, shape of molecule same, dipole moment same(Q) BF3,BCl3(2)Hybridisation of Central atom same, shape ofmolecule same, dipole moment same,isoelectronic species, used in fertiliserpreparation(R) CO2CN22(3) Hybridisation of central atom same, shape ofmolecule same, dipole moment same,isoelectronic species, aromatic(S) C6H6,B3N3H6(4) Hybridisation of central atom same, shape ofmolecule same, but dipole moment different


A

P-4, Q-1, R-2, S-3

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B

P-1, Q-2, R-3, S-4

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C

P-2, Q-3, R-4, S-1

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D

P-3, Q-2, R-1, S-4

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Solution

The correct option is A

P-4, Q-1, R-2, S-3


(p) Hybridisation is Sp3 d, shape of molecule is Trigonal bi pyramidal but μ is not same

(q) Hyb is Sp2, Trigonal planar and μ=0

(r) Hyb is Sp, linear, μ=0, have same electrons (22) and used in the prep of fertiliser (NH3)

(s) Hyb is Sp2, planar, μ=0 , Isoelectronic and aromatic with Huckel’s rule.


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