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Question


pH=XCr2O27CrO24(orange)pH=Y(green)
This change is based on change in pH. Probable values of X and Y cannot be :

A
8, 6
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B
8, 10
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C
4, 6
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D
change is independent of pH
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Solution

The correct options are
B 8, 10
C 4, 6
pH=X=8 or 4 (less than Y)Cr2O27CrO24orangepH=Y=10 or 6 (more than X)green
As dichromate ion changes to chromate in acidic medium( less pH) , whereas chromate changes to dichromate in basic medium ( higher pH)
Lower pH (acidic medium)
Cr2O27<========================>CrO24
Higher pH ( basic medium)

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