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Nucleophilic Addition at the Carbonyl

Benzaldehyde ...

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Benzaldehyde reacts with acetic acid anhydride in presence of sodium acetate at 180°c then the product formed is

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Q. Salicylaldehyde reacts with acetic acid in the presence of concentrated sodium acetate at

180^{o} C

Q. When Benzaldehyde is condensed with acetic anhydride is presence of fused sodium acetate we get

Oxidation of toluene with $C r O_{3}$ to benzaldehyde is carried out in the presence of acetic anhydride. Explain why.

Q. Acetic anhydride reacts with benzene in presence of anhydrous

A l C l_{3}

Q. What happens when:
(a) Acetyl chloride is reduced with hydrogen in presence of barium sulphate associated with palladium.
(b) Benzaldehyde boils with

45

N a O H

.
(c) Ammonia reacts with formaldehyde.
(d) Acetic-Acid reacts with -

P {C l}_{5}

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Nucleophilic Addition at the Carbonyl

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