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Question

Benzene and toluene form nearly ideal solution At 20C, the vapour pressure of benzene is 75 torr and that of toluene is 22 torr. The partial vapour pressure of benzene at 20C for a solution containing 78 g of benzene and 46 g of toluene in torr is

A
50
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B
25
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C
37.5
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D
53.5
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Solution

The correct option is A 50
According to Raoult's law,
PB=PBXBPB=75
XB=7878(7878)+(4692)=11+0.5=11.5PB=75×11.5=50 torr

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