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Question

Benzene on reaction with conc. HNO3 in presence of conc. H2SO4 followed by the treatment of Cl2 in presence of FeCl3, it gives :

A
2chloro1nitrobenzene
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B
1chloro3nitrobenzene
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C
3chloro1nitrobenzene
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D
A mixture of 2chloro and 4chloro1nitrobenzene
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Solution

The correct option is D 3chloro1nitrobenzene
3-Chloro-1-nitrobenzene
Nitro substituents have positive charge on the atom bonded to ring. So the like charges repel each other at ortho and para position as compared to meta substitution. So meta position is favored at 3 chloro in the ring.

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