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Standard XII
Chemistry
Synthesis of Ethers
Benzoic acid ...
Question
Benzoic acid reacts with conc.
H
N
O
3
and conc.
H
2
S
O
4
to give:
A
o-Nitrobenzoic acid
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B
p-Nitrobenzoic acid
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C
m-Nitrobenzoic acid
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D
o,p-Dinitrobenzoic acid
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Solution
The correct option is
C
m-Nitrobenzoic acid
Carboxyl group is a meta directing group for electrophilic aromatic substitution.
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Q.
Arrange the following in decreasing order of acidic strength.
I. Benzoic acid
II. 4-nitrobenzoic acid
III. 3, 4-dinitrobenzoic acid
IV. 4-methoxy benzoic acid
Q.
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Q.
Give the order of acidic character of the following:
i. a.
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ii. a.
P
h
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C
H
b.
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c.
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iii. 2, 6-Di-tert-butyl phenol is a much weaker acid than phenol.
iv. a. Phenol
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Q.
The correct order of acid strengths of benzoic acid (X), peroxybenzoic acid (Y) and p-nitrobenzoic acid (Z) is:
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Benzoic acid reacts with conc.
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to give major product as:
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