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Standard XII
Chemistry
Amines as Bases
Benzylamine i...
Question
Benzylamine is a stronger base than aniline because:
A
the lone pair of electrons on the nitrogen atom in benzylamine is delocalised
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B
the lone pair of electrons on the nitrogen atom in aniline is delocalised
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C
the lone pair of electrons on the nitrogen atom in aniline is not involved in resonance
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D
benzylamine has a higher molecular mass than aniline
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Solution
The correct option is
B
the lone pair of electrons on the nitrogen atom in aniline is delocalised
Benzylamine is a stronger base than aniline because the lone pair of electrons on the nitrogen atom in aniline is delocalised over benzene ring.
Hence, due to resonance in aniline, the lone pair of electron on nitrogen is less available for donation to suitable acid.
However in case of benzylamine (
C
6
H
5
−
C
H
2
−
N
H
2
), the N atom is attached to saturated C atom.
Hence, no resonance is possible and the lone pair of electron can be easily donated.
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Similar questions
Q.
In aniline, the lone pair of electrons on the
N
atom is delocalised over the benzene ring. As a result, the electron density on nitrogen increases.
Q.
Given below are two statements
Statement I : Aniline is less basic than acetamide.
Statement II: In aniline, the lone pair of electrons on nitrogen atom is delocalise over benzene ring due to resonance and hence less available to a proton.
Choose the most appropriate option
Q.
Assertion :
p
K
b
of aniline is more than that of methylamine. Reason: In aniline, the lone pair of electrons on the
N
atom is delocalized over the benzene ring. As a result, the electron density of nitrogen decreases. In contrast, in
C
H
3
N
H
2
(
+
I
)
effect of
C
H
3
increases the electron density on the
N
atom. Therefore, aniline is a weaker base than methylamine and hence its
p
K
b
value is higher than that of methylamine.
Q.
Assertion :In strongly acidic solutions, aniline becomes more reactive towards electrophilic reagents. Reason: The amino group being completely protonated in strongly acidic solution, the lone pair of electrons on nitrogen is no longer available for resonance.
Q.
Assertion :In strongly acidic solutions, aniline becomes more reactive towards electrophilic reagents Reason: The amino group being completely protonated in strongly acidic solution, the lone pair electrons on the nitrogen is no longer avaiable for resonance.
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