Best method of preparing alkyl chloride is:

R O H + S O C l_{2} ⟶

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R O H + P C l_{5} ⟶

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R O H + P C l_{3} ⟶

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R O H + H C l A n h y Z n C l_{2} - ------ \to

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Solution

The correct option is A $R O H + S O C l_{2} ⟶$
Find the reaction from given choices in which product are gaseous and hence, easy to remove.
$R O H + S O C l_{2} ⟶ R C l + S O_{2} ↑ + H C l ↑$
$∵ S O_{2}$ and $H C l$ are gaseous by-products and can be removed easily to get pure alkyl halide.
$∴$ It is the best method for preparation of alkyl halides

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